Exploring Tandem Ruthenium-Catalyzed Hydrogen Transfer and SNAr Chemistry.

نویسندگان

  • Kurt Polidano
  • Benjamin G Reed-Berendt
  • Anaïs Basset
  • Andrew J A Watson
  • Jonathan M J Williams
  • Louis C Morrill
چکیده

A hydrogen-transfer strategy for the catalytic functionalization of benzylic alcohols via electronic arene activation, accessing a diverse range of bespoke diaryl ethers and aryl amines in excellent isolated yields (38 examples, 70% average yield), is reported. Taking advantage of the hydrogen-transfer approach, the oxidation level of the functionalized products can be selected by judicious choice of simple and inexpensive additives.

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عنوان ژورنال:
  • Organic letters

دوره 19 24  شماره 

صفحات  -

تاریخ انتشار 2017